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In a zinc-induced porcine model of testicular dysfunction, zinc induces ferroptosis by regulating mitochondrial autophagy [98]

& Fahey, R.C

Oncogene 28, 12611273

For this interaction to occur, the structural requirement in the enzyme is the presence of a nucleophilic amino acid side-chain close to the glutathione-docking motif and in a crucial position to interact with the electrophilic motif of glutathione acrylate, as shown in Scheme 9

Additionally, treatment of several cancer types with the enzyme asparaginase, or dietary restriction of asparagine, reduces metastasis but does not alter the growth of primary tumors