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1) Oxidative block irreversible, makes NADPH and CO Step 1: G6P + NADP 6-phosphogluconolactone + NADPH via G6PD (rate-limiting) Step 2: lactone + HO 6-phosphogluconate Step 3: 6-PG + NADP ribulose-5-P (Ru5P) + CO + NADPH Net per G6P: 2 NADPH + CO + Ru5P 2) Non-oxidative block reversible sugar shuffling Ru5P ribose-5-P (R5P) or xylulose-5-P (Xu5P) Transketolase (TPP-dependent) moves 2-carbon pieces: Xu5P + R5P sedoheptulose-7-P + GAP

Under zinc-deficient conditions, the downregulation of these genes mediated by the impaired function of Sp1 can lead to cell cycle arrest or abnormal cell cycle progression, ultimately affecting cell growth and proliferation [144, 145]

Exogenous NADPH ameliorates myocardial ischemia-reperfusion injury in rats through activating AMPK/mTOR pathway

Superoxide dismutase (SOD) is an antioxidant enzyme produced in our bodies to neutralize a specific oxygen-derived free radical called superoxide