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Description
Metabolism Pathways of Arachidonic Acids: Mechanisms and Potential Therapeutic Targets

The brown discoloration is due to a condition called "melanonychia," which occurs when the nail has excess melanin, a dark brown or black pigment that colors the hair, skin and iris of the eye

Similarly, Watson et al

La principale mthode repose sur la raction de l'actaldhyde avec la 2,4-dinitrophnylhydrazine, puis analyse de l'hydrazone obtenue par chromatographie liquide haute pression ou chromatographie en phase gazeuse

Because of this, it plays a central role in overall antioxidant defense, well beyond its cosmetic applications
