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The tetrapeptide (Nlel -YEFf) and tripeptide (Nlel -YI) fragments of the Nlel -AnglV analog of AnglV were previously found to be the smallest active fragments capable of overcoming scopolamine-induced cognitive dysfunction in a spatial learning task

It catalyzes the addition of glycine to -glutamylcysteine created by GCL to form GSH, -L-glutamyl-L-cysteinyl-glycine, a reaction again driven by the hydrolysis of ATP

1 In the absence of adequate GSH concentrations, numerous oxidative and nitrosative reactive intermediates persist, including superoxide, hydroxide, peroxide, and peroxynitrite radicals, which all can lead to modification of cellular macromolecules including lipid membranes (measured in vivo by F2-isoprostanes) and DNA adduct formation (measured in vivo by 8-hydroxy-2-deoxyguanosine [8-OHdG])

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10.1093/cvr/cvt139 92 LiZ.HartlF