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This targeted redox signal serves as an early alarm, acutely rewiring metabolic flux, for instance, away from the TCA cycle and towards alternative pathways like glycolysis or glutaminolysis, to meet changing energetic or biosynthetic demands, particularly under stress conditions such as inflammation or ischemiareperfusion [86]

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GSH is incapable of penetrating cell membranes due to its high hydrophilicity and being negatively charged at physiologic pH

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It is also worth noting that the heightened oxidative stress observed in AD can precipitate mutations, deletions and impairments in mtDNA repair mechanisms (85)