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Structure-based insights into the catalytic power and conformational dexterity of peroxiredoxins

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Transsulfuration is necessary for homocysteine/methionine sulfur oxidation Transsulfuration of Hcy to Cys is catalyzed by two pyridoxal 5-phosphate (PLP)-dependent enzymes, cystathionine -synthase (CBS) and cystathionine -lyase (CSE), as shown in Fig

Nicotinamide adenine dinucleotide phosphate (NADPH) donates the electrons in both of these steps via a flavoprotein reductase