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Aquacobalamin (H 2 OCbl) brominated at the C10-position of the corrin reacts with GSH to give Cbl(II) via GSH complexation and subsequent reaction of this complex with a second GSH molecule, whereas unmodified H 2 OCbl generates glutathionyl-Cbl, which is resistant to further reduction by GSH

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Proc Natl Acad Sci U S A 107(5):23312336 May MJ, Leaver CJ (1993) Oxidative stimulation of glutathione synthesis in Arabidopsis thaliana suspension cultures