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333 The 9,12-, 13,16-, and 9,16-dihydroperoxides may be formed from the 9- and 16-hydroperoxides by the same mechanism suggested for autoxidized methyl linoleate that proceeds through pentadienyl radicals
In other words, they can have addictive properties, so suddenly cutting gluten out of your diet can cause strong withdrawal symptoms

Stubbs BJ, Cox PJ, Kirk T, Evans RD, Clarke K
Just for hard-core geeks, the main biologically active compounds are pentacyclic triterpenoid saponins called asiaticoside, madecassoside, asiatic and madecassic acid (also called centellosides)

Randell, J
