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Glutathione is the most abundant intracellular thiol (i.e., a compound containing a sulfhydryl [SH] group) and low molecular weight tripeptide found in living cells

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Thus if increased PKA mediates the decrease in G6PD activity and NADPH level and in turn, these changes cause the high glucose-mediated decrease in the antioxidant enzyme activities of GR, catalase, and SOD as suggested in figure 3, then inhibition of PKA should rescue the glucose-induced increase in these enzymes

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However, its metabolism places a significant burden on the livers detoxification and antioxidant systems , particularly through depletion of glutathione