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Operating at temperatures between 160C and 270C and pressures over 5 MPa, hydrothermal pretreatment leverages auto-hydrolysis, where water ionizes to produce hydronium ions that facilitate selective hydrolysis of ether bonds in lignin and acetyl group in hemicellulose decomposition (Shen et al., 2016), lead to polysaccharide and lignin depolymerization