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In addition, the increased expression and activity of NOX and xanthine oxidase and NOS becoming uncoupled and structurally unstable also lead to increased ROS production [8]

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Beyond its role in reducing oxidative stress, glutathione (GSH) supplementation has been linked to improved insulin sensitivity (how effectively the body responds to insulin), which is associated with a reduced risk of diabetes

The aforementioned activation may consequently result in the release of substance P, neurokinin A, or calcitonin gene-related peptide (CGRP) [16]

So its not innocuous to give you substances to get a nitroglycerin or nitric oxide-like effect